期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2021, 期 6, 页码 951-955出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202001484
关键词
Electrochemical reactions; Enamines; Polysubstituted pyrrole; Cross-coupling; Oxidative annulation
资金
- Zhejiang provincial science and technology department [LGF19B060005]
This novel electrochemical method utilizes enamines for the preparation of pyrrole compounds, providing a simple, efficient, and environmentally friendly approach for organic synthesis.
A conceptually novel method for the preparation of pyrrole is described by electrochemical-oxidation-induced intermolecular annulation via enamines. In a simple undivided cell, based on a sodium acetate-facilitated, polysubstituted pyrrole derivations has been facilely synthesized under external oxidant-free condition. This electrosynthetic approach providing an environmentally benign protocol for C-C bond cross-coupling and oxidative annulation, which features unparalleled broad scope of substrates and practicality.
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