期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2021, 期 2, 页码 309-313出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202001328
关键词
Bimetallic catalyst; Cobalt carbonyl; Formylation; Palladium; Reductive carbonylation
An efficient protocol has been developed for the reductive carbonylation of (hetero) aryl halides and triflates under CO gas-free conditions using Pd/Co-2(CO)(8) and triethylsilane. The mild reaction conditions, enhanced chemoselectivity, and easy access to heterocyclic and vinyl carboxaldehydes highlight its importance in organic synthesis.
An efficient protocol for the reductive carbonylation of (hetero) aryl halides and triflates under CO gas-free conditions using Pd/Co-2(CO)(8) and triethylsilane has been developed. The mild reaction conditions, enhanced chemoselectivity and, easy access to heterocyclic and vinyl carboxaldehydes highlights its importance in organic synthesis.
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