期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2021, 期 4, 页码 701-708出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202001510
关键词
Cyclic amines; Peroxide; Radicals; Sulfones; Sulfonyl hydrazides
资金
- National Natural Science Foundation of China [21602159, 21877085]
- Zhejiang Provincial Natural Science Foundation of China [LY18B020010]
An efficient iodine-mediated coupling reaction of cyclic amines with sulfonyl hydrazides was reported, providing a new route to the synthesis of vinyl sulfone derivatives. Tentative mechanistic studies suggest that this reaction likely proceeds through a radical process.
An efficient iodine-mediated coupling of cyclic amines with sulfonyl hydrazides is reported. This transformation opens a new route to the synthesis of vinyl sulfones derivatives, which is a common structural motif in natural products and pharmaceuticals. Tentative mechanistic studies suggest that this reaction is likely to involve a radical process.
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