4.7 Article

Magnetic graphene-based nanocomposites as highly efficient absorbents for Cr(VI) removal from wastewater

期刊

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
卷 28, 期 12, 页码 14671-14680

出版社

SPRINGER HEIDELBERG
DOI: 10.1007/s11356-020-11634-x

关键词

Magnetic graphene-based composites; Recycling; Regeneration; Adsorption; Heavy metal ions; Mechanism

资金

  1. National Natural Science Foundation of China [51974110, U1803114]
  2. Education Department Science Foundation of Henan Province [19A440002, 19A530002]
  3. Fundamental Research Funds for the Universities of Henan Province [NSFRF180313]
  4. Young Key Teacher Training Foundation of Henan Province's Universities [2017GGJS052]
  5. Key Scientific and Technological Project of Henan Province [202102210183]

向作者/读者索取更多资源

Magnetic graphene-based composites show high adsorption efficiency and excellent recycling and regeneration properties for removing Cr(VI) ions, with a maximum removal efficiency of 99.9% and a high adsorption rate of 98.13% after 10 cycles. These composites have the potential to be effective adsorbents for heavy metal ion removal in environmental protection and restoration.
Due to the merits of their high adsorption and convenient separation, magnetic graphene-based composites have become a promising adsorbent in terms of wastewater treatment. However, recycling and regeneration properties of magnetic graphene-based composites are still a conundrum, which remains to be resolved. Here, Fe3O4/reduced graphene oxide (RGO) (Fe3O4/RGO) nanocomposites were synthesized by one-step solvent-thermal reduction route and used as adsorbents for water purification. It was encouraging to find that the nanocomposites possessed many intriguing properties in removing of Cr(VI) ions, including high adsorption efficiency and excellent recycling and regeneration property. The results indicated that the magnetic separation process of the Fe3O4/RGO nanocomposites only took less than 5 s and the maximum removal efficiency of Cr(VI) reached 99.9% under the optimum experimental conditions. Most significantly, the adsorption rate of Cr(VI) can still be as high as 98.13% after 10 cycles and the single recycle quality of the nanocomposites can maintain at more than 80%. As a result, the Fe3O4/RGO nanocomposites could be a potential adsorbent for removing heavy metal ions effectively, especially in environmental protection and restoration.

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