期刊
ENERGY & FUELS
卷 35, 期 1, 页码 626-635出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.energyfuels.0c03496
关键词
-
资金
- Nation Key Research and Development Program of China [2019YFE0100100]
- Science, Technology and Innovation Commission of Shenzhen Municipality [JCYJ20180507184519927]
- China Postdoctoral Science Foundation [2019M662616]
The study found that copper doping enhanced the activities of iron-based oxygen carriers, but excessive copper would reduce their reactivity due to melting and agglomeration. Hydrogen temperature-programmed reduction (H-2-TPR) analysis, fixed-bed experiments, and density functional theory (DFT) calculations confirmed that Cu promoted the deep reduction of Fe2O3. The oxygen carrier doped with 1 wt % CuO was the most suitable material for CLH, with the highest hydrogen yield sustained at a high and stable level in multiple redox cycles.
Chemical looping hydrogen (CLH) production, or hydrogen production combined with CO2 capture, is becoming an emerging alternative technology that has attracted much attention. Iron-based oxygen carriers were most widely used in CLH. In this study, bi-active component composite metal oxides with Cu-doped Fe2O3/Al2O3 were synthesized. The oxygen carriers were characterized using different methods such as X-ray diffraction (XRD), scanning electron microscopy (SEM), and Brunauer-Emmett-Teller (BET), and their redox and cycle properties in the CLH process were investigated. The results showed that copper doping enhanced the activities of iron-based oxygen carriers, but excessive copper would reduce their reactivity due to melting and agglomeration. Hydrogen temperature-programmed reduction (H-2-TPR) analysis, fixed-bed experiments, and density functional theory (DFT) calculations all confirmed that Cu promoted the deep reduction of Fe2O3. Among them, the oxygen carrier doped with 1 wt % CuO was the most suitable material for CLH, where H-2 yield was the highest and sustained in a high and stable level in multiple redox cycles.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据