Conversion of Injected Forestry Waste Biomass Charcoal in a Blast Furnace: Influence of Pyrolysis Temperature

The objective of this work is to study the influence of pyrolysis temperature on the combustion behavior of biomass-derived charcoal under conditions that simulate tuyere injection operations in a blast furnace ironmaking process. These results are compared with those for conventional pulverized coal. Pinus radiata chips have been pyrolyzed in a screw continuous reactor at 300, 500, 700, and 900 degrees C, and the vapors obtained have been thermally treated in a second reactor at 800 degrees C. The charcoal has been characterized, including its chemical composition as well as its textural characteristics. Tuyere injection combustion behavior tests of the charcoal and pulverized coal have been performed under different oxygen-to-carbon ratios in a batch injection rig reactor at 1700 degrees C for 20 ms, charcoal in its initial sample size distribution (45-2000 mu m) and both ground to 90-125 mu m. It has observed that increasing pyrolysis temperature results in lower charcoal yields, decreasing its volatile matter and oxygen contents and increasing the carbon content. Concerning the influence of temperature, the higher the pyrolysis temperature, the lower the influence of the injection rate on the charcoal combustion is. It has proven that 45-2000 mu m particle size charcoal shows a greater conversion degree than 90-125 mu m ground charcoal in the injection rig reactor, except for 900 degrees C charcoal, regardless of the particle injection rate. The conversion degrees of the 45-2000 mu m particle size charcoal produced at 300, 500, and 700 degrees C are similar, being these data much greater than that of pulverized coal at any injection rate. The conversion degree of 900 degrees C original charcoal is not affected by the increase of oxygen-to-carbon ratio, showing conversion higher than that of pulverized coal for only high injection rates, which include values typically used in industries.

Automated summary

The study investigates the influence of pyrolysis temperature on the combustion behavior of biomass-derived charcoal under conditions simulating tuyere injection operations. Results show that higher pyrolysis temperature leads to lower charcoal yields, decreased volatile matter and oxygen content, and increased carbon content. Charcoal particle size affects conversion degree in the injection rig reactor, with significant differences observed between different temperature charcoal properties.