期刊
ELECTROCHIMICA ACTA
卷 365, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2020.137294
关键词
-
资金
- University of Bologna, Italy
- European Union's Horizon 2020 Research and Innovation Program [696656]
- Italian Ministry of Research (MIUR) [NEWLI2015CL3APH]
A novel electrochemical synthesis method for producing LDHs intercalated with carbon nanomaterials was proposed. The synthesized composites were characterized and analyzed to understand their structure and growth mechanisms. The best performing material showed promising results in the development of a hybrid supercapacitor, emphasizing the importance of low environmental impact systems.
An electrochemical synthesis which has been optimized to produce layered double hydroxides (LDHs) intercalated with carbon nanomaterials is proposed for the first time. It is based on a one-step procedure which contemporaneously allows for the Ni/Al-LDH synthesis, the reduction of graphene oxide (ERGO) and its intercalation inside the structure. The LDH/ERGO composites were thoroughly characterized by a comprehensive multi-techniques approach in order to verify their structure and morphology. The results confirmed that a LDH structure was observed only if the GO concentration was not higher than 0.2 mg/mL. All the characterizations led to propose a theorization of the synthetic and growth mechanisms of the composites. The best performing material was employed as cathode for the development of a hybrid supercapacitor. The device had a discharge specific capacitance of 880 F g(-1). The promising results obtained in this work embrace the necessity of development of low environmental impact systems; in fact, the proposed hybrid supercapacitor is binder-free, safe, composed of earth abundant elements and able to work in aqueous electrolyte. (c) 2020 Elsevier Ltd. All rights reserved.
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