期刊
COORDINATION CHEMISTRY REVIEWS
卷 427, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2020.213586
关键词
Supramolecular; Chalcogen bonding; Secondary bonding; Selenium; Oxygen
资金
- Sunway University Sdn Bhd [STR-RCTR-RCCM-001-2019]
The Cambridge Structural Database was used to evaluate crystals containing Se⋯O chalcogen bonding interactions. These interactions can operate independently of complementary intermolecular interactions, with one-dimensional and zero-dimensional assemblies being the most prominent in around 55% and 30% of cases, respectively. Specific interactions, such as Se⋯O(carbonyl), occur in 50% of cases where they can potentially form.
The Cambridge Structural Database was evaluated for crystals containing Se center dot center dot center dot O chalcogen bonding interactions. These secondary bonding interactions are found to operate independently of complementary intermolecular interactions in about 13% of the structures they can potentially form. This number rises significantly when more specific interactions are considered, e.g. Se center dot center dot center dot O(carbonyl) interactions occur in 50% of cases where they can potentially form. In about 55% of cases, the supramolecular assemblies sustained by Se center dot center dot center dot O(oxygen) interactions are one-dimensional architectures, with the next most prominent being zero-dimensional assemblies, at 30%. (C) 2020 Elsevier B.V. All rights reserved.
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