Synthesis of phosphanaphthalenes and nido-carborane fused six-membered phosphacycles

A simple method to synthesize luminescent lambda(5)-phosphanaphthalenes and zwitterionic nido-carborane fused six-membered phosphacycles was developed from the reaction of ortho-phosphinobenzoaldehydes or ortho-phosphinocarboranylaldehydes with an electron-deficient alkyne, respectively. Similar results were obtained with the imino analogues. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

Automated summary

A simple method for synthesizing luminescent lambda(5)-phosphanaphthalenes and zwitterionic nido-carborane fused six-membered phosphacycles has been developed. The method involves the reaction of ortho-phosphinobenzoaldehydes or ortho-phosphinocarboranylaldehydes with an electron-deficient alkyne, respectively, to achieve similar results with imino analogues. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.