4.6 Letter

Comments on Molecular Chirality in Classical Spacetime: Solving the Controversy about the Spinning Cone Model of Rotating Molecules

期刊

CHEMISTRY-A EUROPEAN JOURNAL
卷 27, 期 4, 页码 1476-1477

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WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202000427

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absolute enantioselection; chirality; optical rotation; parity and time reversal; spinning cone model

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The recent mathematical analysis by Michel Petijean concluded that the Barron/Mislow controversy over the chirality of a non-translating spinning cone is a matter of an arbitrary choice of a conversion factor. This reassessment highlights the different physicochemical properties of a stationary spinning cone and a chiral molecule, leading to the conclusion that Petitjean's analysis is misleading.
A recent mathematical analysis by Michel Petijean aimed at solving the Barron/Mislow controversy concerning the chirality or otherwise of a non-translating spinning cone concluded that both are right: the controversy is a matter of an arbitrary choice of a conversion factor. This reassessment highlights the different physicochemical properties of a stationary spinning cone and a chiral molecule and concludes that Petitjean's analysis is misleading.

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