4.6 Review

The Prospect of Dimensionality in Porous Semiconductors

期刊

CHEMISTRY-A EUROPEAN JOURNAL
卷 27, 期 27, 页码 7489-7501

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202005167

关键词

covalent organic frameworks; dimensionality; organic semiconductors; porous organic polymers; porous semiconductors

资金

  1. Swiss National Science Foundation (SNSF) [200021-175947]
  2. Swiss National Science Foundation (SNF) [200021_175947] Funding Source: Swiss National Science Foundation (SNF)

向作者/读者索取更多资源

The development of silicon-based semiconductors led to the exploration of organic semiconductors, but there are still challenges in achieving efficient charge transfer. While the impact of molecular design is well understood, the influence of dimensionality remains an uncharted area that is crucial for practical utilization in (metal-)organic semiconductors.
With the advent of silicon-based semiconductors, a plethora of previously unknown technologies became possible. The development of lightweight low-dimensional organic semiconductors followed soon after. However, the efficient charge/electron transfers enabled by the non-porous 3D structure of silicon is rather challenging to be realized by their (metal-)organic counterparts. Nevertheless, the demand for lighter, more efficient semiconductors is steadily increasing resulting in a growing interest in (metal-)organic semiconductors. These novel materials are faced with a variety of challenges originating from their chemical design, their packing and crystallinity. Although the effect of molecular design is quite well understood, the influence of dimensionality and the associated change in properties (porosity, packing, conjugation) is still an uncharted area in (metal-)organic semiconductors, yet highly important for their practical utilization. In this Minireview, an overview on the design and synthesis of porous semiconductors, with a particular emphasis on organic semiconductors, is presented and the influence of dimensionality is discussed.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据