期刊
CHEMICAL ENGINEERING JOURNAL
卷 402, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2020.126235
关键词
Low-temperature solid oxide fuel cells; Hydrocarbons; Methane; Internal reforming; Coking; Sulfur poisoning
Solid oxide fuel cells (SOFCs) are important electric generators due to their high energy efficiencies and fuel flexibilities. However, the high operation temperature ( > 800 degrees C) results in high system cost/complexity and poor long-term durability. Recently, decreasing the operating temperature of SOFCs to the low-temperature range (<= 650 degrees C) has attracted intensive attention, especially for the direct utilization of hydrocarbons as fuels. This review summarizes the latest progress in hydrocarbon fueled SOFCs working at <= 650 degrees C, mainly focusing on the challenges and strategies associated with electrolytes, anodes, and cathodes. It highlights the requirement for highly active and carbon/sulfur resistant anode and high ionic conductive electrolytes to gain a superior performance at a lower temperature.
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