期刊
CHEMCATCHEM
卷 13, 期 3, 页码 851-854出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202001669
关键词
n-Butyllithium; hydroboration; nitriles; carbodiimides
资金
- National Natural Science Foundation of China [21671018, 21872005]
The study demonstrates highly efficient and selective hydroboration of nitriles and carbodiimides using n-BuLi as a catalyst with pinacolborane. The reaction shows good functional group tolerance and can be carried out solvent-free under mild conditions. A possible mechanistic pathway for the n-BuLi catalyzed hydroboration of nitriles with HBpin is proposed.
Highly efficient and selective hydroboration of nitriles and carbodiimides with pinacolborane (HBpin) is achieved by using the simple and convenient n-BuLi as a catalyst. Solvent-free and good functional group tolerance under mild conditions have been achieved. A possible mechanistic pathway of the n-BuLi catalyzed hydroboration of nitriles with HBpin is proposed.
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