期刊
CATALYSIS COMMUNICATIONS
卷 149, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.catcom.2020.106257
关键词
Composite oxide; NO-CO redox conversion; H-2-TPR; CO-TPD; Oxygen mobility
资金
- UGC-CSIR NET-JRF
- UGC-New Delhi
The silver and rhodium binary precious metals added composite oxide shows promising effect in achieving 100% conversion of NO and CO at significantly low temperature of 150 degrees C. The mesoporous structure composed of active nano-particles enhances oxygen mobility and CO reactivity on catalyst surface, demonstrating good synergy between active Ag-Rh pairs in catalytic enhancement.
A promising effect of the silver and rhodium binary precious metals added composite oxide was investigated for NO-CO redox reaction. The interaction of Ag and Rh enhanced the catalytic property of the overall composite catalyst which brought to 100% conversion of NO and CO at significantly low temperature of 150 degrees C. Additionally, mesoporous structure composed of such active nano-particles leads in high oxygen mobility and CO reactivity on catalyst surface, showing a good agreement with catalytic performance. Such catalytic enhancement conveys the transfer of electronic cloud from Ag to Rh which is pointing towards good synergy between active Ag-Rh pairs.
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