4.6 Article

A hollow structure WO3@CeO2 catalyst for NH3-SCR of NOx

期刊

CATALYSIS COMMUNICATIONS
卷 149, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.catcom.2020.106252

关键词

Hollow structure catalyst; WO3; CeO2; Low-temperature NH3-SCR

资金

  1. National Natural Science Foundation of China [21876093, 11675098, 11875185]
  2. National Key Research, Development Program [2017YFC0210700, 2018YFC0213400]
  3. Program for Changjiang Scholars and Innovative Research Teamin University [IRT_17R71]

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The development of a novel WO3@CeO2 catalyst with hollow structure using carbon sphere as hard template for NH3-SCR of NOx reaction has shown higher catalytic performance and tolerance due to its high specific surface area, reducible W species, increased specific amount of chemisorbed oxygen species, and acid sites.
Constructing a hollow structured Ce-based catalyst is an effective way to result in an efficient catalytic system for the selective catalytic reduction of NOx using NH3 (NH3-SCR). A WO3@CeO2 catalyst with hollow structure was successfully developed using carbon sphere as hard template, and tested for the NH3-SCR of NOx reaction. The obtained WO3@CeO2 catalyst with hollow structure exhibit higher NOx conversion (88%) than traditional WO3-CeO2 catalyst (40%) at 200 degrees C, and superior SO2 and H2O tolerance at 300 degrees C, given its high specific surface area, reducible W species, increased specific amount of chemisorbed oxygen species and acid sites.

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