4.8 Article

Enhanced corrosion and wear resistance of gradient graphene-CrC nanocomposite coating on stainless steel

期刊

CARBON
卷 174, 期 -, 页码 693-709

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2020.12.007

关键词

Graphene nanocomposite coating; Electrochemical noise; Anticorrosion; Wear resistance; Ball milling

资金

  1. Research Program of Hebei University [521000981397]

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The study demonstrated the preparation of graphene-CrC nanocomposite coatings on stainless steel using mechanical ball milling, significantly improving the corrosion resistance of stainless steel. The graphene coatings were strongly bonded on the stainless steel surface by C-Cr bonding, leading to a remarkable reduction in corrosion rates at temperatures between 293-328K.
The preparation of high-efficiency, stable, and low-cost graphene coating on the stainless steel substrate was highly anticipated but remained a challenge. Here, the graphene-CrC nanocomposite coatings were prepared on the 304 stainless steel ball (SS) by using the simple mechanical ball milling, which is in a gradient structure of graphene-CrC towards outside (G/SS). Notably, the graphene coatings could be strongly bonded on the SS surface by C-Cr bonding, which could provide excellent durability. Corrosion analysis revealed that graphene-CrC coatings would remarkably enhance the anticorrosion property of SS at the range of 293-328 K. The corrosion rates of the G/SS were merely 0.0336 x 10(-4) mm day(-1), which was significantly slower than that of the SS (1.58 x 10(-4) mm day(-1)) at the room temperature. The double-layered coating could slow down the wear rate from 14.1 x 10(-6) mm(3) N-1 m(-1) to 4.82 x 10(-6) mm(3) N-1 m(-1). The present work could light on a straightforward strategy for the development of graphene coatings on metal substrate. (C) 2020 Elsevier Ltd. All rights reserved.

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