期刊
CARBON
卷 171, 期 -, 页码 341-349出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2020.08.055
关键词
Graphene; Copper; Transparent electrode; Solar cell
资金
- National Research Foundation of Korea [NRF-2017R1A2B2012971, NRF-2020R1F1A1075539]
- Ministry of Science and ICT (MSIT) [2019R1H1A2102032]
- Electronics and Telecommunications Research Institute (ETRI) - Korea government [20ZB1200]
- Ministry of Trade, Industry and Energy/Korea Evaluation Institute of Industrial Technology [MOTIE/KEIT 10044412]
- National Research Foundation of Korea [2019R1H1A2102032] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Cu/graphene hybrid films serve as both p-type and n-type transparent conducting electrodes in organic solar cells, with sheet resistance and work function being significantly improved by controlling the thickness of Cu. The films also exhibit wrinkle features and doubled RMS currents, while devices utilizing Cu/graphene electrodes show much higher power conversion efficiencies compared to those with pristine graphene electrodes.
Cu/graphene hybrid films which function as both p-type and n-type transparent conducting electrodes were utilized in conventional and inverted organic solar cells. The value of sheet resistance decreased to similar to 75 Omega/sq for Cu/graphene hybrid films with an optimum thickness of 7 nm of Cu, which constitutes a dramatic improvement compared to graphene alone (similar to 180 Omega/sq). Meanwhile, the work functions of the Cu/graphene hybrid electrodes can also be controlled through the range of 4.84-4.95 eV by changing the amount of Cu which was thermally deposited on top of the graphene layer. In addition, the Cu/graphene films showed wrinkle features with the root-mean-square (RMS) roughness ranging from 1.9-5.8 nm and RMS currents are nearly doubled as a function of the thickness of Cu deposition (similar to 30 nA) by using atomic force microscope (AFM) and conductive-AFM (C-AFM) measurements. Conventional and inverted organic solar cells with 3 nm Cu/graphene hybrid electrodes showed 1.4 and 4.5 times larger power conversion efficiencies (PCE), respectively, than those of the devices with pristine graphene electrodes. (C) 2020 Elsevier Ltd. All rights reserved.
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