期刊
CARBOHYDRATE POLYMERS
卷 251, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2020.117027
关键词
bicomponent cellulose-lignin fibers; NMMO; phase diagram; fiber morphology
资金
- Fraunhofer market-oriented strategic initial research program
This study investigated the direct dissolution and joint spinning of cellulose and lignin from NMMO-water, showing that lignin can dissolve in a range from 30% NMMO to 70% NMMO. Dry-jet wet spinning was achieved for cellulose-lignin compound up to 50% lignin loading, with lignin mainly acting as a filler in the core region of the fiber. The spinnability decreases with increasing lignin content.
The direct dissolution and joint spinning of cellulose and lignin from NMMO-water were investigated by using dissolving pulp and purified KRAFT lignin. Compared to the rather narrow dissolution window of cellulose in the NMMO-water system, lignin with concentrations up to 15 wt.-% was shown to dissolve in a range from 30 % NMMO to 70 % NMMO at room temperature. The quasi-ternary phase diagram of cellulose-lignin-(NMMO-monohydrate) is represented by a cross section at 95 degrees C. Dry-jet wet spinning was realized for the cellulose-lignin compound up to 50 % lignin loading. The spinnability decreases with increasing lignin content. SEM and TEM investigations of the fibers exhibit a core-shell structure with a dense core and a porous shell with lower lignin content. In accordance with the X-ray fiber diagrams, it can be concluded that cellulose governs fiber formation and fiber properties while lignin acts mainly as a filler in the core region.
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