期刊
CARBOHYDRATE POLYMERS
卷 252, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2020.117092
关键词
Cellulose; Emulsions; Microrheology; Diffusing wave spectroscopy; Cryo-scanning electron microscopy
资金
- Swedish Research Council (Vetenskapsradet) [2015-04290]
- Portuguese Foundation for Science and Technology, FCT [PTDC/ASP-SIL/30619/2017, UIDB/05183/2020, CEECIND/01014/2018]
- Technion Russell Berrie Nanotechnology Institute (RBNI)
- Swedish Research Council [2015-04290] Funding Source: Swedish Research Council
- Fundação para a Ciência e a Tecnologia [PTDC/ASP-SIL/30619/2017] Funding Source: FCT
Cellulose-based oil-in-water emulsions were studied to investigate the impact of cellulose concentration and mixing rate on droplet size, microrheological properties, and stability. Cellulose effectively adsorbed at the oil-water interface, forming a protective shell structure that prevented droplet coalescence, while the non-adsorbed cellulose in the aqueous medium enhanced viscosity and overall stability. Higher cellulose concentration and mixing rate resulted in smaller emulsion droplets and increased stability, showcasing a promising methodology for novel emulsion-based formulations through a combination of DWS and cryo-SEM.
Cellulose-based oil-in-water (O/W) emulsions were studied by diffusing wave spectroscopy (DWS) regarding the effect of the cellulose concentration and mixing rate on the average droplet size, microrheological features and stability. Furthermore, the microstructure of these emulsions was imaged by cryo-scanning electron microscopy (cryo-SEM). The micrographs showed that cellulose was effectively adsorbed at the oil-water interface, resembling a film-like shell that protected the oil droplets from coalescing. The non-adsorbed cellulose that was observed in the continuous aqueous medium, contributed to the enhancement of the viscosity of the medium, leading to an improvement in the stability of the overall system. Generally, the higher the cellulose concentration and mixing rate, the smaller the emulsion droplets formed, and the higher was their stability. The combination of both techniques, DWS and cryo-SEM, revealed a very appealing and robust methodology for the characterization and design of novel emulsion-based formulations.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据