期刊
DALTON TRANSACTIONS
卷 45, 期 27, 页码 11101-11108出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt01149g
关键词
-
资金
- CNRS
- ANR agency (program blanc Ironhyc) [12-BS07-0011-01]
- ANR agency (program JCJC Ferracycles) [ANR-15-CE07-0001]
- University of Rennes 1
- Fondation Rennes 1
- Agence Nationale de la Recherche (ANR) [ANR-15-CE07-0001] Funding Source: Agence Nationale de la Recherche (ANR)
A new and efficient method based on the simple metalating reagent Fe(CO)(5) has been developed for the straightforward synthesis of well defined cyclometalled PCP iron carbonyl pincer complexes. The reaction proceeds cleanly under mild conditions at 30 degrees C and UV irradiation. Four hydride pincer complexes are synthesized and fully characterized as well as an intermediate dinuclear species. The new iron complexes are active and selective catalytic precursors for the dehydrogenative borylation of styrene with HBpin.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据