期刊
APPLIED CLAY SCIENCE
卷 199, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.clay.2020.105864
关键词
CuCo2S4 nanotube; NiCoAl hydrotalcite; Hierarchical core-shell structure; Supercapacitor
资金
- Natural Science Foundation of Hunan Province [2020JJ4575, 2019JJ50613]
- Key Research and Development Program of Hunan Province [2018SK20110]
The hierarchical core-shell structure CuCo2S4@NiCoAl-LDH/NF composite with 3D mesoporous network structure was designed and prepared, where the NiCoAl hydrotalcite (NiCoAl-LDH) was as shell, and the CuCo2S4 nanotube array on Ni foam (NF) as core. Owing to the unique architecture and integration of respective merits from each component, the core-shell material displayed a large surface area, high conductivity, short ion diffusion path and rapid interfacial charge transmission. So, the CuCo2S4@NiCoAl-LDH/NF electrode showed superior electrochemical performances with a high specific capacitance of 938C g(-1) (1876 F g(-1)) at 1.0 A g(-1) and excellent cycling stability (retention of 91.11% after 5000 cycles at 5 A g(-1)). The eminent performances suggested that the CuCo(2)S4@NiCoAl-LDH/NF with 3D mesoporous network core-shell structure was one of the candidates as electrodes for high-performance supercapacitors.
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