期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 278, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2020.119332
关键词
Oxygen reduction reaction; Magnetic effect; L1(0)-PtFe alloy; Model catalyst; Orbital coupling
资金
- Excellent One Hundred project of Beijing Jiaotong University
- Fundamental Research Funds for the Central Universities [2018JBZ107, 21905019]
- National Natural Science Foundation of China [21905019, 91961125]
- Key Program for International S&T Cooperation Projects of China from the Ministry of Science and Technology of China [2018YFE0124600]
- Chemistry and Chemical Engineering Guangdong Laboratory [1932001, 1932004]
- KAKENHI [18H03787]
- NIMS
It is important to improve the oxygen reduction reaction (ORR) performance of Pt by alloying it with first-row transition metals (M: e.g., Fe, Co, Ni). It is known that the ligand, strain, and ensemble effects govern the ORR performance. However, the intrinsic magnetic characteristics of PtMs have rarely been focused on in ORR investigations. Here, we employed a hard-magnet L1(0)-ordered PtFe nanopillar film (L1(0)-PtFe NF) as model catalyst to uncover the catalyst's magnetic effect on the ORR. We report a five-fold enhancement of the catalytic efficiency of magnetized L1(0)-PtFe(M) NF compared with unmagnetized one. Further investigations demonstrate that the coverage of chemisorbed oxygen on catalyst surface, especially the primary Pt d(yz)-O-2 pi* coupling, manipulated by the catalyst's magnetic field is the key factor for the ORR regulation. This work thus paves the way for the implementation of magnetic effect towards the precise regulation in broad catalysis applications.
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