期刊
DALTON TRANSACTIONS
卷 45, 期 2, 页码 448-452出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt03891j
关键词
-
资金
- SFB 813 (Chemistry at Spin Centers)
- Jurgen Manchot Stiftung
- Studienstiftung des deutschen Volkes
- National Science Foundation [CHE-1123815]
Radical-based transformations are an attractive target for the development of catalytic processes due to ease of radical generation, high functional group tolerance and selectivity of bond-forming reactions. In spite of these appealing features, the potential of radicals as key intermediates in catalysis remains largely untapped. Herein we present recent work that exploits the innate ability of titanocene-based catalysts to undergo both oxidative addition and reductive elimination in single electron steps. We further demonstrate that tuning the redox properties of the titanocene-based catalyst can be used to develop efficient catalytic free radical processes including tetrahydrofuran synthesis, and radical arylation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据