期刊
DALTON TRANSACTIONS
卷 45, 期 29, 页码 11807-11816出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt01484d
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资金
- Key Laboratory of Advanced Ceramics and Machining Technology, Ministry of Education (Tianjin University)
Zn-3(Nb1-xTax)(2)O-8 (x = 0.02-0.10) ceramics were prepared via a solid-state reaction route and the dependence of their microwave dielectric properties on their structural characteristics were investigated. XRD patterns show that a single Zn3Nb2O8 phase with layered crystal structures was formed in ceramic samples with 0.02 <= x <= 0.10. The Raman spectrum was used for the first time to analyze the vibrational phonon modes of the Zn3Nb2O8 samples. Based on P-V-L dielectric theory, the intrinsic factors that influence the microwave dielectric properties were systematically investigated. According to the calculated results, the experimental dielectric constant had a close relationship with the theoretical dielectric constant. The Nb-site lattice energy was found to be a vital factor in explaining the change of the Q x f values. While the Nb-site bond energy increases, the vertical bar tau(f)vertical bar value decreases which indicates that higher bond energy would result in a more stable system. This work presents a novel method to investigate the intrinsic factors that influence microwave dielectric properties.
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