期刊
DALTON TRANSACTIONS
卷 45, 期 39, 页码 12585-12589出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt01872f
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资金
- National Science Foundation [CHE-1301132, CHE-1349048]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1301132] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1349048] Funding Source: National Science Foundation
The electrochemical properties of two Ni(NNN)X-2 pincer complexes are reported where X = Cl or Br and NNN is N, N'-(2,6-diiso-propylphenyl)bis-aldiminopyridine. Cyclic voltammetry under 1 atm of CO2 suggests electrocatalytic CO2 reduction activity, however, bulk electrolysis shows a poor Faradaic efficiency for CO evolution with a high Faradaic yield for H-2 evolution.
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