4.8 Article

Charge-Promoted Self-Metalation of Porphyrins on an Oxide Surface

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Article Chemistry, Multidisciplinary

Charge-Promoted Self-Metalation of Porphyrins on an Oxide Surface

Larissa Egger et al.

Summary: This study investigates the self-metalation of porphyrin molecules on ultrathin MgO(001) films, revealing that charge transfer promotes the self-metalation process. By tuning the work function of the substrate, the charge and metalation state of porphyrin molecules on the surface can be controlled.

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