期刊
DALTON TRANSACTIONS
卷 45, 期 20, 页码 8494-8499出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt01301e
关键词
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资金
- Office of Naval Research (ONR)
- Defense Threat Reduction Agency (DTRA)
- NSF
- Hydrocarbon Research Foundation
The reactions of acetonitrile, propionitrile, butyronitrile, N,N-dimethylaminoacetonitrile, benzonitrile, o-tolunitrile and 1,4-dicyanobenzene with HF/AsF5 or HF/SbF5 in anhydrous HF result in protonation of the nitrile. The obtained nitrilium ions were isolated as [AsF6](-), [SbF6](-) and [Sb2F11](-) salts and characterized by multinuclear NMR and vibrational spectroscopy, and their X-ray crystal structures.
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