Spin-Crossover Properties of an Iron(II) Coordination Nanohoop

Addition of the bipyridyl-embedded cycloparaphenylene nanohoop bipy[9]CPP to [Fe{H2B(pyz)(2)}] (pyz=pyrazolyl) produces the distorted octahedral complex [Fe(bipy[9]CPP){H2B(pyz)(2)}(2)] (1). The molecular structure of 1 shows that the nanohoop ligand contains a non-planar bipy unit. Magnetic susceptibility measurements indicate spin-crossover (SCO) behaviour with a T-1/2 of 130 K, lower than that of 160 K observed with the related compound [Fe(bipy){H2B(pyz)(2)}(2)] (2), which contains a conventional bipy ligand. A computational study of 1 and 2 reveals that the curvature of the nanohoop leads to the different SCO properties, suggesting that the SCO behaviour of iron(II) can be tuned by varying the size and diameter of the nanohoop.

Automated summary

The addition of bipyridyl-embedded cycloparaphenylene nanohoop to an iron(II) complex leads to a distorted octahedral structure with spin-crossover behavior. Computational studies suggest that the size and curvature of the nanohoop play a critical role in determining the SCO properties of the iron(II) complex.