期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 13, 页码 7290-7296出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202015837
关键词
alkenes; aryl radicals; dehydrogenation; hydrogenation atom transfer; redox-active ligands
资金
- Max-Planck-Society
- ETH Zurich [ETH-45 19-2]
- China Scholarship Council
- Projekt DEAL
The study introduces a novel strategy for the catalytic, intermolecular dehydrogenation of alkanes using a ruthenium catalyst, which involves a combination of a redox-active ligand and a sterically hindered aryl radical intermediate to unleash the new strategy. Mechanistic investigations have been conducted to provide a conceptual framework for the further development of this new catalytic dehydrogenation system.
The direct dehydrogenation of alkanes is among the most efficient ways to access valuable alkene products. Although several catalysts have been designed to promote this transformation, they have unfortunately found limited applications in fine chemical synthesis. Here, we report a conceptually novel strategy for the catalytic, intermolecular dehydrogenation of alkanes using a ruthenium catalyst. The combination of a redox-active ligand and a sterically hindered aryl radical intermediate has unleashed this novel strategy. Importantly, mechanistic investigations have been performed to provide a conceptual framework for the further development of this new catalytic dehydrogenation system.
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