期刊
DALTON TRANSACTIONS
卷 45, 期 11, 页码 4528-4533出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt03751d
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资金
- NRF [2012R1A4A1027750, 2013R1A2A2A01067771]
- Grants-in-Aid for Scientific Research [26410100] Funding Source: KAKEN
- National Research Foundation of Korea [21A20151513130, 2012R1A4A1027750, 2013R1A2A2A01067771] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
19-membered and a 38-membered macrocycles obtained as a mixture via respective [1 : 1] and [2 : 2] cyclisations were separated and their coordination behaviours with copper(I) iodide were investigated. One of the notable products isolated is a tetranuclear bis(macrocycle) complex with the larger macrocycle adopting a double decker type structure. Furthermore, removal of the lattice solvent molecules in the above complex in air motivates the displacement of the double decker units along the a-axis by sliding in a single-crystal-to-single-crystal manner.
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