期刊
DALTON TRANSACTIONS
卷 45, 期 25, 页码 10289-10296出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt01411a
关键词
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资金
- Natural Science Foundation of China [21401078, 21571083]
- Government of Zhejiang province
The reaction of ligand L, N,N-bis(pyridin-2-ylmethyl) acetamide, with five transition metal salts, FeCl3 center dot 6H(2)O, CuCl2 center dot 2H(2)O, Cu(ClO4)(2)center dot 6H(2)O, ZnCl2 and K2PtCl4/KI, produced five metal complexes, [(mu-O) (FeClL')(FeCl3)] (1), [CuLCl2] (2), [CuBPA(ClO4)(CHCN)] ClO4 (3), [ZnLCl2] (4) and [PtLI2] (5), where L' = 1-(2,4,5-tri(pyridin-2-yl)-3-(pyridin-2-ylmethyl) imidazolidin-1-yl) ethanone which formed in situ, and BPA = bis(pyridin-2-ylmethyl) amine. The ligand and complexes were characterized by a variety of spectroscopic techniques including X-ray single crystal diffraction where applicable. Depending on the metal ion and auxiliary ligand of the complex, the acetyl group of the ligand L could be either intact or cleaved. When ferric chloride hexahydrate was used, the deacetylation proceeded even further and a novel heterocyclic compound (L') was formed in situ. A possible mechanism was proposed for the formation of the heterocyclic compound found in complex 1. Our results indicate that to cleave effectively an amide bond, it is essential for a metal centre to bind to the amide bond and the metal centre is of sufficient Lewis acidity.
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