期刊
DALTON TRANSACTIONS
卷 45, 期 18, 页码 7875-7880出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6dt00827e
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资金
- VNU-HCM [A2015-50-01-HD-KHCN]
- United States Office of Naval Research Global [N62909-15-1N056]
A zirconium-based metal-organic framework, an effective heterogeneous catalyst, has been developed for the Friedel-Crafts benzoylation of aromatic compounds under microwave irradiation. Constructed by a Zr(IV) cluster and a linker 1,4-bis(2-[4-carboxyphenyl]ethynyl) benzene (H2CPEB), the MOF, possessing large pores and high chemical stability, was appropriate for the enhancement of Lewis acid activity under microwave irradiation. The reaction studies demonstrated that the material could give high yields for a few minutes and maintain its reactivity and structure over several cycles.
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