4.7 Article

Synthesis of Oxazolidinones by a Hypervalent Iodine Mediated Cyclization of N-Allylcarbamates

期刊

ADVANCED SYNTHESIS & CATALYSIS
卷 363, 期 6, 页码 1646-1650

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202001451

关键词

Iodine; Addition to alkenes; Cyclization; Hypervalent compounds; Allylic compounds; C-O bond formation

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  1. University of Huddersfield

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This study presents the preparation of oxazolidinones by the hypervalent iodine mediated cyclization of allylcarbamates, allowing for a versatile range of substrates to be converted into substituted oxazolidinones ready for further transformations. Derivatization of the products at both ends is demonstrated in addition to a preliminary attempt at the enantioselective formation of an oxazolidinone using a chiral iodane.
The preparation of oxazolidinones by the hypervalent iodine mediated cyclization of allylcarbamates is described. A versatile range of substrates can be converted into substituted oxazolidinones primed for further transformations. Derivatization of the products at both ends is demonstrated. A preliminary attempt at the enantioselective formation of an oxazolidinone using a chiral iodane is also presented.

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