期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 363, 期 3, 页码 833-837出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202001202
关键词
sulfonyl hydrazides; alcohols; sulfinic esters; transition-metal-free; radical pathway
资金
- National Natural Science Foundation of China [20702051]
- Natural Science Foundation of Zhejiang Province [LY13B020017]
A new protocol for the synthesis of sulfinic esters via esterification of sulfonyl hydrazides with alcohols using NaHSO3 as the promoter has been developed. This method offers mild transition-metal-free reaction conditions, an inexpensive and readily available reagent, and operational simplicity. Controlled experiments suggest that the transformation likely proceeds through a radical pathway.
We have developed a protocol for the NaHSO3-promoted esterification of sulfonyl hydrazides with alcohols for the synthesis of sulfinic esters. Various sulfonyl hydrazides could be converted to the corresponding sulfinic esters in good to high yields. The merits of this protocol include mild transition-metal-free reaction conditions, an inexpensive and available reagent, and operational simplicity. Controlled experiments reveal that this transformation probably undergoes via a radical pathway.
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