期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 363, 期 4, 页码 980-1006出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202001219
关键词
Heterocycles; Multicomponent reactions; One-pot processes; Quinoxalines
资金
- Fonds der Chemischen Industrie
Quinoxalines are nitrogen-containing bicyclic heterocycles with diverse biological activities and luminescence properties. Their syntheses involve a range of multicomponent methods, such as Ugi-reactions, leading to the development of novel reactions and sequences. Diversity-oriented synthesis and transition metal catalyzed multicomponent reactions offer efficient pathways to quinoxalines and quinoxaline-containing moieties.
Quinoxalines represent bicyclic nitrogen-containing heterocycles with a wide array of applications. They exhibit a multitude of biological activities relevant in medicinal chemistry as well as a plethora of luminescence properties. Quinoxaline syntheses exploit the whole raft of multicomponent syntheses from domino to sequential or consecutive reactions, harvesting well-known synthetic concepts and reactions, such as Ugi-reactions, but also leading to the development of novel reactions and sequences. Diversity-oriented synthesis and transition metal catalyzed multicomponent reactions open efficient pathways to quinoxalines and quinoxaline-containing moieties in a one-pot fashion. This review outlines the underlying reaction-based principles of multicomponent syntheses of quinoxalines and summarizes recent developments quinoxaline-directed MCRs, illustrating their scopes.
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