期刊
ACS APPLIED MATERIALS & INTERFACES
卷 13, 期 4, 页码 5895-5906出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.0c22986
关键词
interfacial impedance; MPNP model; equivalent circuit model; space charge layer capacitance; polarization effect
资金
- China Scholarship Council (CSC)
- TU Darmstadt
Understanding and quantifying the interfacial impedance between the solid electrolyte and the electrode is crucial for the design of solid-state batteries. The proposed new equivalent circuit model, based on the MPNP model, includes space charge layer resistance and polarization resistance, providing a more accurate explanation for impedance behavior at low frequencies compared to traditional capacitor models.
Understanding the interfacial impedance between the solid electrolyte and the electrode is a critical issue for the design of solid-state batteries. We propose a new equivalent circuit model that treats the interface not only as a capacitor but also includes the space charge layer resistance and the resultant polarization resistance. Moreover, the elements of the circuit model are quantified by the physical quantities based on the recently proposed modified Planck-Nernst-Poisson (MPNP) model, which includes the effect of the unoccupied regular lattice sites (vacancies) in the electro-diffusion problem and takes both the ion and electron contributions into the account. We provide a new analytical solution for the space charge layer capacitance. Comparative numerical results demonstrate that our proposed model with additional polarization resistance can explain well the real impedance tail at the low-frequency region, for which the pure capacitor interface model fails. The model is verified against the experimental impedance spectra of LiPON.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据