期刊
FRONTIERS IN ENERGY RESEARCH
卷 8, 期 -, 页码 -出版社
FRONTIERS MEDIA SA
DOI: 10.3389/fenrg.2020.00148
关键词
lignin nano-particles; porous carbon; thermal conductivity; hydrothermal carbonization; graphene
资金
- National Natural Science Foundation of China [31730106]
- Natural Science Foundation of Jiangsu Province [BK20180772]
Lignin nano-particles (LNPs) exhibit properties that distinguish them from the production of other lignin-based materials. However, little research has been performed to investigate whether porous carbons produced from LNPs exhibit a performance superior to those derived from untreated lignin. In this study, lignin was fabricated into LNPs and used to prepare high-performance porous carbons with enhanced thermal conductivities compared to that of carbons from neat lignin. Two different preparation protocols were employed: direct pyrolysis and hydrothermal carbonization followed by pyrolysis. Carbons obtained from 100 to 300 nm LNPs possessed more graphene-like structures than carbons from unaltered lignin. In addition, carbons prepared using a combination of hydrothermal carbonization and pyrolysis exhibited higher specific surface areas (108.81-220.75 m(2)/g) and total pore volumes (0.098-0.166 cm(3)/g) than those prepared via direct pyrolysis. In addition, LNP-derived carbons exhibited superior thermal conductivities (0.45 W/mK) and thermal conductivity rates (0.51 degrees C/s). This work provides the useful finding that superior graphene-like porous carbons can be produced by transforming lignin into LNP and then hydrothermally carbonizing the resulting material prior to pyrolysis.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据