期刊
ACS APPLIED ENERGY MATERIALS
卷 3, 期 9, 页码 8937-8945出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.0c01403
关键词
composite films; capacitors; PVDF; energy density; energy storage; breakdown strength
资金
- KRICT basic research fund [SS2021-40]
- Korea Institute of Energy Technology Evaluation and Planning (KETEP) - Korea Government Ministry of Trade, Industry and Energy [20202010100010]
- Korea Evaluation Institute of Industrial Technology (KEIT) [20202010100010] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The fabrication of a core-shell structure is an effective method of obtaining a composite film with a high energy density. Herein, we prepared a new type of composite film with high energy density and energy efficiency by using silica-coated core-shells on poly(vinylidene fluoride) (PVDF) particles that comprised a high proportion of polar phases rather than inorganics with high dielectric constants. We prepared PVDF particles with a high proportion of the beta-phase using emulsion polymerization. Subsequently, we prepared PVDF@SiO2 core-shell particles by coating silica using the sol-gel method. The resultant PVDF@SiO2-PVDF exhibited a low reduction in the dielectric constant because of the lower amount of silica than that in other dense silica particles, which was verified through dielectric constant measurements and theoretical calculations. In addition, when the PVDF@SiO2 particle contained 40 wt % silica, a high breakdown strength of 598.95 MV/m was confirmed. Therefore, we verified that the PVDF@SiO2-PVDF composite film has a high discharge energy density of 12.051 J/cm(3) when the PVDF@SiO2 is 40 wt %. In addition, the domain size is limited by the silica shell, resulting in a high energy efficiency of 88.22%, which indicated a potential for the utilization of the composite film in energy storage devices. These results offer a novel strategy for the development of polymer-based capacitors with high energy densities and efficiencies.
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