4.7 Article

High-performance bimetallic Ni-Mn phosphate hybridized with 3-D graphene foam for novel hybrid supercapacitors

期刊

JOURNAL OF ENERGY STORAGE
卷 31, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.est.2020.101584

关键词

Hybrid device; Metal phosphate; Supercapacitor; Energy storage; Graphene, composite

资金

  1. South African Research Chairs Initiative (SARChI) of the Department of Science and Technology
  2. National Research Foundation (NRF) of South Africa [61056]
  3. University of Pretoria
  4. NRF through the SARChI in Carbon Technology and Materials
  5. Al Fashir University, Sudan

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Nickel-manganese phosphate/graphene foam (GF) composite was successfully synthesized through a simple and direct hydrothermal approach, serving as highly efficient electrodes for hybrid device. Ni and Mn are both redox metals owing to their multiple oxidation states however, Ni-based materials possess higher capacity due to its strong faradic mechanism while Mn-based materials offer pseducapacitive nature and GF for its ability to im-prove the surface area as well as the electrical conductivity of the composite. Consequently, the prepared NiMn (PO4)(2)/GF composite achieved a maximum specific capacity of 97 mAh g(-1) at 0.5 A g(-1) in a 3-electrode configuration setup compared to 63 mAh g(-1) for the pristine material. Thus, NiMn(PO4)(2)/GF considered as a positive electrode in a hybrid device with carbon derived from Capsicum (bell pepper) seeds peppered-activated carbon (ppAC) as a negative electrode. The hybrid device reported a maximum energy density of 35.42 Wh kg(-1) corresponding to a power density of 538 W kg(-1) at 0.5 A g(-1). The NiMn(PO4)(2)/GF//ppAC hybrid device also showed high stability of 97.8% capacity retention over 10,000 cycles at 6 A g(-1), similar to 93% float time efficiency after 120 h and could still preserve similar to 1.17 V against its initial cell potential of 1.5 V after 60 h of self discharge. The outstanding performance of NiMn(PO4)(2)/GF material in a half and full cell makes it a good candidate for supercapacitor application.

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