A photo-capacitive sensor operational from 6 K to 350 K with a solution printable, thermally-robust hexagonal boron nitride (h-BN) dielectric and conductive graphene electrodes

A new exfoliation route is introduced for overcoming the drawback of horn-tip exfoliation by combining it with slow magnetic stirring for hexagonal boron nitride (h-BN) bulk crystals. Inkjet printing of h-BN is then conducted, where various patterns were designed and printed and a change from translucent to-opaque was observed with increasing printing passes from 1 pass (0.417 mu m thickness) to 5 passes (1.964 mu m thickness). The increase in the E-2g peak intensity in the Raman spectra with the thickness of h-BN printed films is demonstrated, which is attributed to an increase in collective photon number as thickness increases. The effect of temperature on the Raman spectra of printed h-BN patterns is studied and the first-order temperature coefficient chi is derived indicative of the thermal properties of printed h-BN films at elevated temperatures. The red-shift of the E2g peak with temperature arises from the variation in the interplanar vibrational frequency with material expansion due to heating. The chi values of -0.033 cm(-1) /K and -0.028 cm(-1) /K for 20 and 30 passes of printed h-BN is suggestive of thermally stable h-BN after annealing. All inkjet-printed graphene/h-BN/graphene capacitors were fabricated and the leakage current density, JLeakage, was measured to be similar to 72 nA/mm(2), while the capacitance density was measured to be similar to 2.4 mu F/cm(2). Finally, the influence of temperature, frequency, and light irradiation on the performance of graphene/h-BN-based capacitive structures were explored using capacitance density voltage measurements. The ratio, C-on/C-off, between the capacitance density in the illumination ON state, Con, and in the illumination OFF or dark state, C-off, was also calculated for the graphene/h-BN capacitor fabricated with 30 printing passes. The C-on/C-off was similar to 1.6 at 6 K and similar to 1.4 at 350 K (measured at 1 kHz frequency), suggesting the potential of this 2D graphene/h-BN heterostructure to serve as a photo capacitive sensing element for printed electronics applications over a wide thermal regime from 6 K to 350 K. (c) 2020 Elsevier Ltd. All rights reserved.