Melt Stable Functionalized Organosolv and Kraft Lignin Thermoplastic

A shift towards an economically viable biomass biorefinery concept requires the use of all biomass fractions (cellulose, hemicellulose, and lignin) for the production of high added-value products. As lignin is often underutilized, the establishment of lignin valorization routes is highly important.In-houseproduced organosolv as well as commercial Kraft lignin were used in this study. The aim of the current work was to make a comparative study of thermoplastic biomaterials from two different types of lignins. Native lignins were alkylate with two different alkyl iodides to produce ether-functionalized lignins. Successful etherification was verified by FT-IR spectroscopy, changes in the molecular weight of lignin, as well as(13)C and(1)H Nuclear Magnetic Resonance (NMR). The thermal stability of etherified lignin samples was considerably improved with theT(2%)of organosolv to increase from 143 degrees C to up to 213 degrees C and of Kraft lignin from 133 degrees C to up to 168 degrees C, and glass transition temperature was observed. The present study shows that etherification of both organosolv and Kraft lignin with alkyl halides can produce lignin thermoplastic biomaterials with low glass transition temperature. The length of the alkyl chain affects thermal stability as well as other thermal properties.