期刊
CHEM
卷 6, 期 11, 页码 3022-3037出版社
CELL PRESS
DOI: 10.1016/j.chempr.2020.08.009
关键词
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资金
- University of Trieste
- University of Padova
- INSTM
- Italian Ministry of Education MIUR [2017PBXPN4]
- Spanish Ministry of Science, Innovation and Universities, MICIU [PID2019-108523RB-I00]
- CariPARO Foundation SYNERGY
- GREEN C-C STARS starting grant
- European Social Fund, Operational Programme 2014/2020 FriuliVenezia Giulia [FP1799043001]
- Seal of Excellence @unipd PLACARD
- Spanish State Research Agency [MDM-2017-0720]
Carbon nanodots stand as the missing link between the molecular and the nanoscale world, owing to the unique molecular-like behavior emerging from their synthetic precursors. A converging set of analytical and spectroscopic data yields a precise inventory of the surface reactive groups of amine-rich carbon dots (NCDs-1). As a result, NCDs-1 provide a multi-functional nano-platform that is able to covalently activate carbonyl groups, form iminium-ions and enamine intermediates, and efficiently promote diverse aminocatalytic transformations in water. Remarkably, the catalytic activity of carbon dots can also govern the stereoselectivity in the bond-forming event. Indeed, the use of chiral carbon dots (NCDs-7) as catalysts affords the final aldol products with significant enantiomeric excess. The successful implementation of carbon nanostructures into chemical roles so far restricted to molecular systems opens new avenues for advanced applications where the nanoscale and the molecular realms will merge and complement each other.
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