期刊
CHEMNANOMAT
卷 7, 期 1, 页码 44-49出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cnma.202000536
关键词
LSPR effect; W18O49; photocatalytic H-2 generation
资金
- National Natural Science Foundation of China [51672113, 21975110, 21972058, 51772291, 21875048]
- Outstanding Youth Project of Guangdong Natural Science Foundation [2020B1515020028]
- Science and Technology Research Project of Guangzhou [202002010007]
- Taishan Youth Scholar Program of Shandong Province
Integrating oxygen-vacancy-rich W18O49 as a plasmon antenna with CdS can enhance the photocatalytic H-2 generation activity under visible light, achieving a higher efficiency compared to CdS alone. This enhancement is attributed to the improved light-harvesting ability and faster charge separation caused by the LSPR effect of W18O49 plasmon with rich oxygen vacancies and an S-scheme transfer mechanism.
Broad-spectrum-driven photocatalysis remains a challenging pursuit for light-chemical energy conversion. Integrating plasmonic nanostructures with localized surface plasmon resonance (LSPR) effect as light absorber onto photocatalyst can realize broad spectral response as well as promote light to energy conversion. Herein, oxygen-vacancy-rich W18O49 as plasmon antenna was coupled with CdS to form an S-scheme CdS/W18O49 heterojunction demonstrating photocatalytic H-2 generation activity under a broad-spectrum light irradiation. Upon exposure to visible light, the CdS/W18O49 heterojunction illustrates the best photocatalytic H-2 generation rate of 5.9 mmol g(-1) h(-1), which is 2.6 times higher than CdS; and its external quantum efficiency achieves 0.17% and 0.05% at 550 and 650 nm, respectively. This activity enhancement is attributed to the enhanced light-harvesting ability and faster charge separation induced by the LSPR effect of the W18O49 plasmon with rich oxygen vacancies and S-scheme transfer mechanism. This work will be beneficial to develop non-metal plasmons assisted broad-spectrum-response photocatalysts.
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