期刊
CURRENT ORGANIC CHEMISTRY
卷 20, 期 13, 页码 1359-1369出版社
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1385272820666151210000010
关键词
Imidazole N-oxides; synthetic methods; isomerization; [3+2]-cycloaddition; heterocyclization; ionic liquids; fluorinated compounds; chiral compounds
资金
- National Science Center (Cracow, Poland) [2012/07/N/ST5/01873, 2014/13/B/ST5/04004]
The 2-unsubstituted 1H-imidazole 3-oxides, considered as 'nitrone-like' azaheterocycles, are well known as versatile building blocks, useful for the preparation of more complex systems containing an imidazole moiety. Their applications in diverse reactions, such as isomerization to corresponding imidazol-2-ones, [3+2]-cycloadditions, sulfur transfer reactions leading to imidazole-2-thiones, heterocyclizations leading to fused heterocyclic systems, as well as cross coupling reactions are discussed. New methods for the preparation of enantiomerically pure 1H-imidazole 3-oxides and their applications in asymmetric reactions, synthesis of room temperature ionic liquids and biologically active compounds are also reviewed.
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