4.5 Review

Nucleophilic Addition of Cyclopropenes

期刊

CURRENT ORGANIC CHEMISTRY
卷 20, 期 18, 页码 1862-1877

出版社

BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1385272820666160331235409

关键词

Cyclopropanes; cyclopropenes; nucleophilic addition; nucleophiles; strain release

资金

  1. Russian Foundation for Basic Research [15-03-02661]

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This review encompasses addition reactions of cyclopropenes proceeding with retention of the small ring as well as cascade transformations involving ring-opening. Formal nucleophilic substitution of halocyclopropanes operating via a dehydrohalogenation-addition mechanism with the formation of cyclopropene intermediates is also discussed. Relevant literature published in the period of 2005-2015 is surveyed.

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