期刊
MATERIALS RESEARCH EXPRESS
卷 7, 期 9, 页码 -出版社
IOP PUBLISHING LTD
DOI: 10.1088/2053-1591/abb90e
关键词
photocatalysis; ZnO; p-n junction; photogenerated; wastewater; MB dye
资金
- Adama Science and Technology University (ASTU) [ASTU/AS-R/001/2019]
The water pollution due to industrial effluents causes a great health problem. Hence, it is important to treat wastewater before discharging to the environment. In this work, water hyacinth (Eichhornia Crassipes) plant extract mediated ZnO, CO3O4, and p-CO3O4/n-ZnO composite catalysts were synthesized by green co-precipitation routes. The resulting samples were characterized by x-ray diffractometer (XRD), scanning electron microscope (SEM), Fortier transform infrared (FT-IR), and with other instruments. The catalytic activities of ZnO, Co3O4, and Co3O4/ZnO were tested for MB dye degradation under visible light irradiation. The catalytic degradation of MB with p-CO3O4/n-ZnO composite catalyst was 95.5%; while 72% and 79% of MB dye was degraded by ZnO and Co(3)O(4)catalysts, respectively. The kinetic rate constants (k) in the degradation of MB dye with ZnO, Co3O4, and p-CO3O4/n-ZnO composite catalysts were also 0.014 min(-1), 0.018 min(-1), and 0.028 min(-1), respectively. The results showed that the presence of plant extract during the synthesis of the catalysts makes the catalyst more active and enhances the catalytic performances. Moreover, the formation of p-n junction in the p-CO3O4/n-ZnO catalyst also facilitates the photogenerated electron-hole separation and further enhances the catalytic efficiency. Hence, the formation of p-n junction is the key factor for enhancing the photodegradation of MB dye under visible light irradiation and the plant extract mediated catalyst synthesis also further improves its performance.
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