Interfacial routes to colloidal gelation

Colloidal gelation is a rheological transition from fluid-like to solid-like viscoelasticity in a particulate suspension and is often instigated by causing the net interparticle interaction to be attractive. In this article, three routes to colloidal gelation that have been discovered recently and involve interfacial phenomena at a fluid interface are reviewed. As in conventional systems, gelation is due to a percolating particle network that imparts elasticity to the mixture, but the network formation involves interfacial particle jamming or bridging, or capillary interactions along or across interfaces, in a mixture of immiscible fluids. Gelation imparts mechanical stability to these multiphase mixtures and paves the way for their use as templates for the synthesis of functional, microstructured materials and composites. The gel mechanical properties are mediated by the interfacial forces and the mixture's microstructure, and therefore show different dependencies on particle volume fraction across the three systems. (C) 2016 Elsevier Ltd. All rights reserved.