期刊
POLYMERS
卷 12, 期 9, 页码 -出版社
MDPI
DOI: 10.3390/polym12091928
关键词
copolymerization; omega-pentadecalactone; poly(omega-pentadecalactone); polyurethane copolymers; shape memory
资金
- European Regional Development Fund
- Higher Education Institutional Excellence Programme of the Ministry of Human Capacities in Hungary
- European Union
- [GINOP-2.3.2-15-2016-00041]
- [GINOP-2.3.3-15-2016-00021]
In this report, the synthesis of poly(omega-pentadecalactone) (PPDL) (co)polymers and their incorporation into polyurethanes (PUs) are reported. Optimal conditions for the ring-opening polymerization (ROP) of omega-pentadecalactone (PDL) using dibutyltin dilaurate catalyst were established. For the synthesis of linear and crosslinked PUs, 50 kDa poly(epsilon-caprolactone) (PCL) and 1,6-hexamethylenediisocyanate (HDI) were used. The obtained polyurethanes were characterized by Attenuated Total Reflectance Fourier-Transform Infrared spectroscopy (AT-FTIR), differential scanning calorimetry (DSC), and dynamical mechanical analysis (DMA). The DMA of the selected sample showed a rubbery plateau on the storage modulus versus temperature curve predicting shape memory behavior. Indeed, good shape memory performances were obtained with shape fixity (R-f) and shape recovery (R-r) ratios.
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