期刊
ACS MACRO LETTERS
卷 9, 期 11, 页码 1563-1568出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsmacrolett.0c00486
关键词
-
资金
- Air Force Office of Scientific Research [FA9550-16-1-0017]
- National Science Foundation [CMMI 19-33932]
In this work, a simple method is reported for control over initiation in frontal ring-opening metathesis polymerization (FROMP). This noncontact approach uses 375 nm light to excite Grubbs' second-generation catalyst in the presence of a phosphite inhibitor. Photoinitiated FROMP of dicylcopentadiene (DCPD) displays a similar cure profile to that of its thermally initiated counterpart, yielding a robust polymer with high glass transition temperature. Furthermore, this system is applied to enhance reaction rates in conventional ring-closing metathesis reactions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据