Conductivity and Oxidation Behavior of Fe-16Cr Alloy as Solid Oxide Fuel Cell Interconnect Under Long-Stability and Thermal Cycles

Conductivity and oxidation behavior of Fe-16Cr alloy were investigated under long-term stability operation at 750 degrees C and thermal cycles from room temperature to 750 degrees C. The results showed that the area specific resistance (ASR) of Fe-16Cr alloy increased over time and reached about 56.29 m omega cm(2)after 40,000 h of long-term stability operation at 750 degrees C by theoretical calculation. The ASR of Fe-16Cr remained about 11 m omega cm(2)after 52 thermal cycles from room temperature to 750 degrees C. The analysis of structure showed that the oxidized phase on the surface of Fe-16Cr was mainly composed of Cr(2)O(3)and FeCr(2)O(4)spinel phase under long-term stability operation at 750 degrees C. While the Cr(2)O(3)phase was mainly observed on the surface of Fe-16Cr alloy after 52 thermal cycles, the oxidation rates of Fe-16Cr alloy were 0.0142 mu m h(-1)and 0.06 mu m cycle(-1)under long-term stability operation and under thermal cycle, respectively. The property of Fe-16Cr alloy with 2.6 mm thickness met the lifespan requirement of interconnect for solid oxide fuel cell (SOFC) stacks. The Cr element all diffused onto oxidation surface, indicating that it was necessary to spray a coating on the surface to avoid poisoning cell cathode of SOFCs. Two 2-cell stacks were assembled and tested to verify the properties of Fe-16Cr alloy as SOFC interconnect under long-term stability operation and thermal cycle condition.

Automated summary

The conductivity and oxidation behavior of Fe-16Cr alloy were studied under long-term stability operation at 750 degrees C and thermal cycles. The results showed that the alloy performed well at 750 degrees C, making it suitable for use as an interconnect material in SOFCs.